Material Safety Data Sheet

PROPANE & WHOLESALE PROPANE


Material Identification and Use


Manufacturer's Name Canada Imperial Oil Limited
An affiliate of Exxon Corporation
Manufacturer's Address 111 St. Clair Avenue West
P.O. Box 4029, Station "A"
Toronto, Ontario, Canada  M5W 1K3
Emergency Phone Number 1-800-424-9300 (Chemtrec)
Supplier's Address P.O. Box 86, Tonawanda, NY  14151
Supplier Emergency Phone # (519) 339-2145  (24 hours)
Supplier Non Emergency Phone # (416) 441-7455  (8am-5pm M-F) Tech. Information
Product Name HD-5 Propane (Odorized)
Product Code 13603
Product Category Multi-Purpose fuel or chemical feedstock.
Product Use Colourless gases composed mainly of C3 hydrocarbons stored and handled as liquids under pressure.

Ingredients


Components Percentage CAS Number Occupational Exposure Limit (Exxon Recommends)
Propane 90 - 99 74-98-6 1000 ppm TWA for 8 hours/day, and 1500 ppms for a 15 minute short term exposure (STEL).
Propylene 1 - 5 115-07-1 1000 ppm 8 hour TWA and 3000 ppm 15 minute STEL.
Ethane 0 - 5 74-84-0
Isobutane 0 - 2.5 75-28-5 800 ppm
Butanes 0 - 2.5 68513-65-5 800 ppm (1900 mg/m3)
 

This product is hazardous as defined in 29 CFR1910. 1200.
OSHA HAZARD
All components of this product are listed on the U.S. TSCA inventory.

Physical Data



The following data are approximate or typical values
and should not be used for precise design purposes.
Odour and Appearance Colourless gas, stenched to allow detection of leaks.
Viscosity 0
Vapor Pressure  850 psi at 59 F (15 C)  (RVP)
Vapour Density (Air=1) 1.52
Evaporation Rate (n-BUTYL ACETATE=1) > 1
Boiling Point -42.00°C  (-43.6°F)
Pour, Congealing or Melting Point N/A
pH N/A
Solubility in H20 @ 1 ATM 77 F (25 C) Negligible

Fire-Fighting Measures


"Empty" Container Warning "Empty" containers retain residue (liquid and/or vapor) can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, SPARKS, STATIC ELECTRICITY OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue is difficult to remove. "Empty" drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All other containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. For work on tanks refer to Occupational Safety and Health Administration regulations, ANSI Z49.1, and other governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated operations.
Extinguishing Media and Fire-Fighting Procedures Use water spray to cool fire exposed surfaces and to protect personnel. Shut off fuel to fire if possible to do so without hazard. If a leak or spill has not ignited use water spray to disperse the vapors. Do not extinguish flames at leak because possibility of uncontrolled explosive re-ignition exists. Cut off fuel and/or allow fire to burn out. Extinguish small residual fires with dry chemical powder or water spray. Try to cover liquid spills with foam.
Flashpoint and Method of Determination -153° F  (-103° C) ,  COC ASTM D92
Auto Ignition Temperature 810° F (432° C)
Flammable Limits in Air % B. V. Upper 9.5 %
Flammable Limits in Air % B. V. Lower 2.4 %
NFPA - Hazard Class Health:1  Fire:4  Reactivity:0
HMIS Health:1  Fire:4  Reactivity:0
Decomposition Products Under Fire Conditions Smoke, carbon monoxide, carbon dioxide.
Handling Precautions / General Hazards Extremely flammable; material will readily ignite at ambient temperatures. Flammable Gas; may readily form flammable mixtures at or above the flash point. Toxic gases will form upon combustion. Static discharge; material can accumulate static charges which may cause an incendiary electrical discharge. 
Auto-refrigeration; drains may become plugged and valves may become inoperable because of the formation of ice due to expanding vapours or vapourizing liquids.
Special Precautions Respiratory and eye protection required for fire fighting personnel. A self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. For small outdoor fires, which can easily be extinguished with a portable fire extinguisher, use of an SCBA may not be required.

Reactivity Data


Chemical Stability Stable
Incompatible Materials Strong oxidizing agents.
Hazardous Polymerization Material is not known to polymerize.

Health Hazard Information


Routes of Entry
Skin Contact Exposure to rapidly expanding gas or vapourizing liquid may cause frostbite (cold burns).
Eye Exposure to rapidly expanding gas or vapourizing liquid may cause frostbite (cold burns) and permanent eye damage.
Inhalation May cause central nervous system disorder (e.g. loss of coordination, weakness, fatigue, mental confusion and blurred vision) and/or damage. Breathing high vapour concentrations (saturated vapours) for a few minutes may be fatal. Saturated vapours can be encountered in confined spaces and/or under conditions of poor ventilation. May cause irritation, breathing failure, coma and death without any warning odour being sensed.
Ingestion Not considered to be a hazard.

Emergency and First Aid Procedures


Eyes In case of cold burns caused by rapidly expanding gas or vapourizing liquid, get prompt medical attention.
Skin In case of cold burns caused by rapidly expanding gas or vapourizing liquid, get prompt medical attention.
Inhalation If overcome by vapor, remove from exposure and call a physician immediately. If breathing is irregular or has stopped, start resuscitation, administer oxygen, if available.
Ingestion First Aid is not applicable.

Preventative Measures


Exposure Controls The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces. Use explosion-proof ventilation equipment.
Personal Protection In open systems where contact is likely, wear gas-proof goggles, face shield, chemical resistant overalls, and appropriate thermal/chemical gloves. Where skin and eye contact is unlikely, but may occur as a result of short and/or periodic exposures, wear long sleeves, chemical resistant gloves, gas-proof goggles, and a face shield. Where concentrations in air may exceed the occupational exposure limits of exposure reduction are not adequate, approved respirators may be necessary to prevent overexposure by inhalation.
Note N/A

Environmental Procedures


Spills or Releases Land Spill: 
Eliminate source of ignition. Keep public away. Prevent additional discharge of material, if possible to do so without hazard. Vapours or dust may be harmful or fatal. Warn occupants of downwind areas. Allow to evaporate. Consult an expert on disposal of recovered material. Ensure disposal in compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill.

Water Spill:
Eliminate all sources of ignition. Vapours or dust may be harmful or fatal. Warn occupants and shipping in downwind areas. Allow to evaporate from surface. Consult an expert on disposal of recovered material. Ensure disposal in compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill.

Disposal Clean up action should be carefully planned and executed. Shipment, storage and/or disposal of waste materials are regulated and action to handle or dispose of spilled or released materials must meet all state, local, and federal rules.
Storage Keep containers closed. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. Store as pressurized liquid in a pressure vessel. Store and load the container at normal (up to 38 deg C) temperature and at atmospheric pressure. Material will accumulate static charges which may cause a spark. Static charge build-up could become an ignition source. Use proper grounding procedure. Imperial Oil has no knowledge how its customers will handle, store, transfer, distribute, or use odourized propane and therefore makes no warranty regarding the propane or ethyl mercaptan after the custody of these materials passes to the customers. It is recommended that Imperial Oil's customers provide their employees and subsequent customers with information regarding the characteristics of propane, how those characteristics relate to the employees or customers use inducing the limitation of any odourant including ethyl mercaptan. With proper handling, transportation and storage, adding a chemical odourant such as ethyl mercaptan has proven to be a very effective warning device, but all odourants have certain limitations. The effectiveness of the odourant may be diminished by a person's sense of smell, by competing odours and by oxidation which may cause a potentially dangerous situation. Further safety related information is contained on the Material Safety Data Sheet.
Industry experience has shown that natural gas streams may contain trace amounts of radon, a naturally occurring radioactive gas, and radioactive particulate decay products which can accumulate in process equipment and storage vessels. These materials emit gamma, alpha, and beta forms of radiation. Since gamma radiation can penetrate the walls of intact equipment a potential for exposure could exist at or adjacent to the external surface of process equipment that contain radon-enriched process streams or accumulated deposits of radon decay products. Equipment emitting gamma radiation at dose rates above background should be assumed to be contaminated with internal deposits of alpha-and-beta-emitting radon decay products. Measures should be taken to preclude the inhalation or ingestion of alpha-beta-emitting materials. Before performing maintenance on contaminated equipment, all process shut-down and the opening of equipment for repair operations. This time will allow the gamma radiation does rates to be reduced to background levels. Maintenance personnel should wear appropriate personal protective equipment and follow recommended industrial hygiene/safety and environmental procedures in accordance with prevailing regulations and industry guidelines.

ELECTROSTATIC ACCUMULATION HAZARD: Yes, use proper grounding procedures.


Transport Information


Transportation Incident Information For further information relative to spills resulting from transportation incidents, refer to latest Dept. of Transportation Emergency Response Guidebook for Hazardous Materials Incidents DOT P 5800.3.
U.S. DOT Hazardous Materials Shipping Description Transported by highway or rail:

Bulk packaging (capacity greater than 119 gallons):
Liquefied Petroleum Gas, 2.1, UN 2075

Non-bulk packaging (capacity less or equal to 119 gallons):
Liquefied Petroleum Gas, 2.1, UN 2075



Transported by Air or Marine Vessel:

Bulk and Non-bulk packaging:
Liquefied Petroleum Gas, 2.1, UN 2075


Toxicological Information


Variability Among Individuals Health studies have shown that many petroleum hydrocarbons and synthetic lubricants pose potential human health risks which may vary from person to person. As a precaution, exposure to liquids, vapors, mists or fumes should be minimized.
Acute Toxicity Data The above evaluation of hazard is based on knowledge of the toxicity of the material's components.

Regulatory Information



The following may be useful in complying with various state and federal laws
and regulations under various environmental statutes.

 
Reportable Quantity (RQ), EPA Regulation 40 CFR 302 (CERCLA Section 102) Not Applicable
Threshold Planning Quantity (TPQ), EPA Regulation 40 CFR 355 (SARA Sections 301-304) No toxic chemical is present greater than 1% or 0.1% (carcinogen).
Toxic Chemical Release Reporting, EPA Regulation 40 CFR 372 (SARA Section 313) No toxic chemical is present greater than 1% or 0.1% (carcinogen).
Hazardous Chemical Reporting, EPA Regulation 40 CFR 370 (SARA Sect. 313-312): EPA Hazard Classification Code:
 
Acute Hazard
Chronic Hazard
Fire Hazard
Pressure Hazard
Reactive Hazard
Y
N
Y
Y
N
OSHA Required Label Information: In compliance with hazard and right-to-know requirements, the following OSHA Hazard Warnings should be found on label, bill of lading or invoice accompanying this shipment.

DANGER!
EXTREMELY FLAMMABLE
ASPHYXIANT
MATERIAL REDUCES OXYGEN AVAILABLE FOR BREATHING.
PROLONGED CONTACT MAY CAUSE FROSTBITE.

Note: Product label may contain non-OSHA related information also.


Preparation Date of Material Safety Data Sheet


Prepared By NOCO - Amy Princess 
Phone number of Preparer 1-800-229-6626
Date Prepared 11/16/2000
Revised Date

Disclaimer


Information presented herein has been compiled from information provided to us by our suppliers and other sources considered to be dependable and is accurate and reliable to the best of our knowledge. Nothing herein is to be construed as recommending any practice or the use of any product in violation of any patent or in violation of any law or regulation. It is the users' responsibility to determine the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us.